(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine
CAS: 167416-28-6
Molecular Formula: C36H50FeP2
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine - Names and Identifiers
| Name | (R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine |
| Synonyms | Josiphos SLJ003-1 JOSIPHOS SL-J003-1 (R)1[(1S)2(di-C-hexylphosphino)ferrocen. ]et-dicyclohexylphos (R,R)-1-DICYCLOHEXYLPHOSPHINO-2-[1-(DICYCLOHEXYLPHOSPHINO)ETHYL]FERROCENE (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (R)-1-[(1S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine (R)-(-)-1-[(S)-2-Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine (R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE |
| CAS | 167416-28-6 |
| InChI | InChI=1/C31H51P2.C5H5.Fe/c1-25(32(26-15-6-2-7-16-26)27-17-8-3-9-18-27)30-23-14-24-31(30)33(28-19-10-4-11-20-28)29-21-12-5-13-22-29;1-2-4-5-3-1;/h14,23-29H,2-13,15-22H2,1H3;1-5H;/t25-;;/m1../s1 |
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine - Physico-chemical Properties
| Molecular Formula | C36H50FeP2 |
| Molar Mass | 600.59 |
| Specific Rotation(α) | -139° ±4° (c 0.5, CHCl3) |
| Appearance | Powder |
| Color | orange |
| Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine - Risk and Safety
| Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | 24/25 - Avoid contact with skin and eyes. |
| WGK Germany | 3 |
| FLUKA BRAND F CODES | 1-10 |
| HS Code | 29310099 |
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine - Introduction
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl phenyl], is an organic compound, the chemical formula is cZoverh and the ethyl fep₂ ligand, in which the iron atom is bound to the ferrocene ligand and the dicyclohexylphosphine ligand.
The properties of this compound are as follows:
-Appearance: Colorless solid
-Melting Point: about 150-155 ℃
-Solubility: Soluble in common organic solvents.
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl] has important applications in organic synthesis:
-Catalyst: It can be used as a chiral modifier to catalyze asymmetric synthesis reactions, such as allylation reactions, isomerization reactions, etc.
-Metal organic chemistry: It can be used as a ligand of transition metal complexes and participate in organic metal chemical reactions.
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl] is generally prepared by the following steps:
1. Combine ferrocene and ethyldicyclohexylphosphine in a chemical reaction to generate the desired intermediate.
2. The intermediate is further processed, purified and crystallized to obtain the pure compound.
Regarding safety information, because the toxicity and danger of the compound are related to the specific experimental conditions and use, it must be operated in a laboratory environment with experimental technology and corresponding equipment. When using the compound, strictly follow the safety procedures and wear appropriate personal protective equipment, such as lab gloves, goggles and protective clothing. If you intend to use this compound, please refer to the safety data sheet (SDS) of the compound or consult a professional chemical-related organization to ensure safe handling and storage.
The properties of this compound are as follows:
-Appearance: Colorless solid
-Melting Point: about 150-155 ℃
-Solubility: Soluble in common organic solvents.
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl] has important applications in organic synthesis:
-Catalyst: It can be used as a chiral modifier to catalyze asymmetric synthesis reactions, such as allylation reactions, isomerization reactions, etc.
-Metal organic chemistry: It can be used as a ligand of transition metal complexes and participate in organic metal chemical reactions.
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl] is generally prepared by the following steps:
1. Combine ferrocene and ethyldicyclohexylphosphine in a chemical reaction to generate the desired intermediate.
2. The intermediate is further processed, purified and crystallized to obtain the pure compound.
Regarding safety information, because the toxicity and danger of the compound are related to the specific experimental conditions and use, it must be operated in a laboratory environment with experimental technology and corresponding equipment. When using the compound, strictly follow the safety procedures and wear appropriate personal protective equipment, such as lab gloves, goggles and protective clothing. If you intend to use this compound, please refer to the safety data sheet (SDS) of the compound or consult a professional chemical-related organization to ensure safe handling and storage.
Last Update：2024-04-10 22:29:15
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Product Name: (R)-1-[(1S)-2-(Dicyclohexylphosphino)Ferrocenyl]Ethyldicyclohexylphosphine Visit Supplier Webpage Request for quotation
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CAS: 167416-28-6
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View History
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine
2-(4-(苄氧基)苯基)-2-甲基丙酸
23647-14-5
32833-96-8
3724-10-5
1757-42-2
2-(4-(苄氧基)苯基)-2-甲基丙酸
23647-14-5
32833-96-8
3724-10-5
1757-42-2